Supported Catalysts and Their Applications

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The need to improve both the efficiency and environmental acceptability of industrial processes is driving the development of heterogeneous catalysts across the chemical industry, including commodity, specialty and fine chemicals and in pharmaceuticals and agrochemicals. Drawing on international research, "Supported Catalysts and their Applications" discusses aspects of the design, synthesis and application of solid supported reagents and catalysts, including supported reagents for multi-step organic synthesis, selectivity in oxidation catalysts, mesoporous molecular sieve catalysts, and the use of Zeolite Beta in organic reactions. In addition, the two discrete areas of heterogeneous catalysts (inorganic oxide materials and polymer-based catalysts) that were developing in parallel are now shown to be converging, which will be of great benefit to the whole field. Providing a snapshot of the state-of-the-art in this fast-moving field, this book will be welcomed by industrialists and researchers, particularly in the agrochemicals and pharmaceuticals industries. TOC:Selectivity in Oxidation Catalysis / The Development and Applicationof Supported Reagents for Multi-step Organic Synthesis / MesoporousMolecular Sieve Catalysts / Relationships between Reactivity and LongRange Structural Order/Disorder / Zeolite Beta and Its Uses in OrganicReactions / Chiral Mesoporous Hybrid Organic-Inorganic Materials inEnantioselective Catalysis / Immobilised Lewis Acids and their Use inOrganic Chemistry / Influence of Zeolite Composition on CatalyticActivity / Synthesis of Soluble Libraries of Macrocycles fromPolymers: Investigations of Some Possible Screening Methods UsingPolymers / Immobilised Catalysts and their Use in the Synthesis ofFine and Intermediate Chemicals / Catalytic Aziridination andEpoxidation of Alkene Using Modified Microporous and MesoporousMaterials / Enantioselective Alkylation of Benzaldehyde by Diethylzincwith (-) Ephedrine Supported on MTS. A New Class of More EfficientCatalysts / Supported Perfluoroalkanedisulphonic Acids as Catalysts inIsobutane Alkylation / Polymer Immobilised Tempo (PIPO): An EfficientCatalytic System for Environmentally Benign Oxidation of Alcohols /The Preparation and Functionalisation of (Vinyl)Polystyrene PolyHIPE.